Low-temperature redetermination of aquachloridotriphenyltin(IV)–1,10-phenanthroline (1/1)
نویسنده
چکیده
The crystal structure of the title compound, [Sn(C(6)H(5))(3)Cl(H(2)O)]·C(12)H(8)N(2), which was refined in the triclinic space group P [Fu, Gao, Ma & Zhang (2005 ▶). Chin. J. Synth. Chem. 13, 55-57], has been redetermined in the monoclinic space group C2/c from low-temperature diffraction measurements. The Sn atom is five-coordinate in a trans-C(3)SnClO trigonal-bipyramidal geometry; the coordinated water mol-ecule forms a pair of hydrogen bonds to the nitro-gen heterocycle.
منابع مشابه
Redetermination of bis(acetylacetonato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)manganese(II)
In the crystal structure of the title compound, [Mn(C5H7O2)2(C12H8N2)], the Mn(2+) cation is coordinated by one bidentate 1,10-phenanthroline ligand and two acetyl-acetonate anions within a slightly distorted N2O4 octa-hedron. The asymmetric unit consists of one Mn(2+) cation situated on a twofold rotation axis, one half of a 1,10-phenanthroline ligand and one acetyl-acetonate anion. In compari...
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